To use a specific encoding when working with XDocument, you can create an XDeclaration.
Samples
C# Sample
XDocument xDoc = new XDocument(); xDoc.Declaration = new XDeclaration("1.0", "ISO-8859-1", "");
VB.NET Sample
Dim xDoc As New XDocument() xDoc.Declaration = New XDeclaration("1.0", "ISO-8859-1", "")
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